Open the Player's Profile on PlayFab
Click the large "Run Cloud Script" button at the top
Select "GrantInventoryItemDatas" from the "Function name" dropdown
Replace everything in the input area with the text given copied from this page. Recommend using Select All (Ctrl+A) before pasting to ensure all text is replaced.
Click "Run Cloud Script" button at the bottom
Given items will now be in their Inbox
You can send yourself these items using the same flow with your own Player ID to test if it works & how it looks before sending it to a player!